Synthesis of a Polydispersed Polybutadiene Latex. Direct Method for High-Solid Polybutadiene Emulsion Preparation
نویسندگان
چکیده
منابع مشابه
1,2-Polybutadiene Latices by Catalytic Polymerization in Aqueous Emulsion
Catalytic aqueous polymerization of butadiene by the cobalt catalyst system [Co(C8H13)(C4H6)]/CS2 affords colloidally stable latices of highly crystalline syndiotactic 1,2-polybutadiene (Tm ) 190 °C, ∆Hc ) 60 J/g, Mw ∼ 105 g/mol, 97% 1,2, 3% 1,4-cis). Catalyst modification with reagents containing electrophilic carbon atoms (e.g., aromatic formamides) strongly decreases polymer crystallinity (T...
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Polybutadiene nanoparticles were synthesized via batch emulsion polymerization of butadiene in the presence of potassium persulfate, disproportionate rosinate potassium cation and t-dodecyl mercaptane as initiator, emulsifier and chain transfer agent, respectively. Polymerization reaction was performed at different temperatures (60, 70 and 80 °C). Conversion was measured at the various time int...
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ژورنال
عنوان ژورنال: Polymer Journal
سال: 1987
ISSN: 0032-3896,1349-0540
DOI: 10.1295/polymj.19.863